Not sure what you are trying to do here, the CoronaVolumeMtl wouldn't be a good fit for leaves in any situation I can think of.
Are you trying to set up a cube, and then have a 3D material that makes leaves appear inside it? If so, that would not be possible - bitmaps only have 2D information and not 3D information, so there would be no bitmap that could "scatter" the leaves through the volume (you'd have just one leaf texture, projected planar throughout the material).
If you are just trying to texture a single leaf, CoronaVolumeMtl would not be the right choice (it has no surface for reflections etc.) and a regular CoronaMtl with translucency would be the way to go, or SSS there if you felt like it.
Anyway, let us know more about what you have in mind here, as I am not clear on that :)